Vibrational relaxation and triggering of the non-equilibrium vibrational decomposition of CO$_2$ in gas discharges

Abstract

Non-equilibrium vibrational dissociation of CO$_2$ at low translational-rotational temperatures $T$ is investigated computationally for conditions of microwave induced plasmas. Semi-analytic treatment of vibrational relaxation in CO$_2$ in shock tube and acoustic experiments is summarized. A state-to-state vibrational kinetics model applied for the simulations is benchmarked and adjusted to the relaxation times obtained in gas dynamic experiments. The governing parameter $Q/n^2_0$ has been introduced, where $Q$ is the specific volumetric power coupled in plasma and $n_0$ is the initial number density of CO$_2$. The modelling results indicate a rapid increase of the rate of the primary dissociation process CO$_2$ + M $\to$ CO + O + M when $Q/n^2_0$ exceeds some critical value. A simple analytic calculation of $\left( Q/n^2_0 \right)_{crit}$ is proposed which agrees well with the numerical results. At $T$=300 K the estimated $\left( Q/n^2_0 \right)_{crit} \eqsim 6\cdot10^{-40}$~W$\cdot$m$^3$.