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arXiv · 2209.01573

Evolution of Local Structures in Alkali-Borate Glasses

Richard Kerner·Dina-Maria dos Santos-Loff·Ana Cristina Rosa
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Abstract

We analyze the dependence of relative proportion of various characteristic clusters in binary alcali-borate glasses on modifier's concentration $x$. A pure $B_2O_3$ glass contains a huge amount of boroxol rings and some amount of boron atoms in between, linking the boroxol rings via oxygen bonds. The addition of the $Na_2O$ modifier creates four-coordinated borons, but the resulting network glass remains totally connected. We study local transformations that lead to creation of new configurations like tetraborates, pentaborates, diborates, etc., and set forth a non-linear differential system similar to the Lotka-Volterra model. The resulting density curves of various local confugurations as functions of $x$ are obtained. Then the average rigidity is evaluated, enabling us to compute the glass transition temperature $T_g(x)$ for a given value of $x$

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Richard Kerner, Dina-Maria dos Santos-Loff, Ana Cristina Rosa. 2022-09-04. Evolution of Local Structures in Alkali-Borate Glasses. https://arxiv.org/abs/2209.01573

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