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arXiv · 2212.02489

Effect of Nano-Confinement on NMR Relaxation of Heptane in Kerogen from MD Simulations and Measurements

Arjun Valiya Parambathu·Walter G. Chapman·George J. Hirasaki·Dilip Asthagiri·Philip M. Singer
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Abstract

Kerogen-rich shale reservoirs will play a key role during the energy transition, yet the effects of nano-confinement on the NMR relaxation of hydrocarbons in kerogen are poorly understood. We use atomistic MD simulations to investigate the effects of nano-confinement on the $^1$H NMR relaxation times $T_1$ and $T_2$ of heptane in kerogen. In the case of $T_1$, we discover the important role of confinement in reducing $T_1$ by $\sim$3 orders of magnitude from bulk heptane, in agreement with measurements of heptane dissolved in kerogen from the Kimmeridge Shale, without any models or free parameters. In the case of $T_2$, we discover that confinement breaks spatial isotropy and gives rise to residual dipolar coupling which reduces $T_2$ by $\sim$5 orders of magnitude from bulk heptane. We use the simulated $T_2$ to calibrate the surface relaxivity and thence predict the pore-size distribution of the organic nano-pores in kerogen, without additional experimental data.

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Arjun Valiya Parambathu, Walter G. Chapman, George J. Hirasaki, Dilip Asthagiri, Philip M. Singer. 2022-12-05. Effect of Nano-Confinement on NMR Relaxation of Heptane in Kerogen from MD Simulations and Measurements. https://arxiv.org/abs/2212.02489

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