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arXiv · 2309.05757

Electron-detachment cross sections for O$^-$ + N$_2$ near the free-collision-model velocity threshold

A. A. Martínez·M. M. Sant'Anna·G. Hinojosa
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Abstract

We present measurements of the total projectile-electron-loss cross sections in O$^-$ + N$_2$ collisions in the energy range from 2.5 to 8.5 keV. Two different techniques, beam attenuation and the growth rate, are employed. The difference between the values obtained with the two methods is explained under the hypothesis of a contribution from anionic metastable auto-detaching states. Under this hypothesis, the long-standing question of a strong disagreement among reported measurements at the low-energy range is also explained. The cross sections measured using the growth-rate method show a threshold behavior. We analyze the cross-section velocity dependence in the framework of a collision between a quasi-free electron, loosely bound to the projectile, and the molecular target. Within the free collision model, we deduce and test a simple analytical expression for the expected velocity threshold taking into account the angular distribution of electron velocities within the anion.

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A. A. Martínez, M. M. Sant'Anna, G. Hinojosa. 2023-09-11. Electron-detachment cross sections for O$^-$ + N$_2$ near the free-collision-model velocity threshold. https://doi.org/10.1103/physreva.109.032806

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