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arXiv · 2310.08963

$^{13}$C NMR observation of a nonmagnetic charge-ordered state in the organic conductor $\kappa$-(ET)$_{2}$Hg(SCN)$_{2}$Cl

M. Urai·K. Miyagawa·S. A. Torunova·N. Drichko·E. I. Zhilyaeva·K. Kanoda
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Abstract

We investigated the local magnetism of the organic conductor, $\kappa$-(ET)$_{2}$Hg(SCN)$_{2}$Cl, with a quasi-triangular lattice of weakly dimerized molecules through $^{13}$C NMR spectroscopy. The NMR spectra and nuclear relaxation show that charge disproportionation occurs, associated with the metal-insulator transition at 31 K. The relaxation rate indicates that the paramagnetic spins in the insulating phase undergo a transition into a spin-singlet ground state with the emergence of orphan spins, a possible valence-bond-glass state. The present results are in high contrast to the spin-cluster paramagnetism of the electric dipole-liquid candidate, $\kappa$--(ET)$_{2}$Hg(SCN)$_{2}$Br, having nearly identical material parameters. This fact indicates that these two systems are on the verge between distinct phases in both charge and spin degrees of freedom; a spin-singlet charge-ordered state versus a spin-active Mott insulating state, competing with each other on a triangular lattice of dimerized sites.

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M. Urai, K. Miyagawa, S. A. Torunova, N. Drichko, E. I. Zhilyaeva, K. Kanoda. 2023-10-13. $^{13}$C NMR observation of a nonmagnetic charge-ordered state in the organic conductor $\kappa$-(ET)$_{2}$Hg(SCN)$_{2}$Cl. https://doi.org/10.1103/k13b-4ch4

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