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arXiv · 2401.05040

Temporal evolution of interparticle potentials of PMMA colloids in CHB/decaline

Marcel Rudolf·Andreas Zumbusch
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Abstract

Colloidal dispersions composed of polymethylmetacrylate particles dispersed in a mixture of cyclohexylbromide and decalin find widespread use as model systems in optical microscopy experiments. While the system allows simultaneous density and refractive index matching, preparing particles with hard potentials remains challenging and strong variations in the physical parameters of samples prepared in the same manner are common. Here, we present data on the measurement of forces between individual pairs of particles over the course of tens of days using a blinking optical tweezer method. Our results show that the variations in the particle properties are indeed caused by a temporal evolution of the particles' charging. Additional measurements of the influence of tetrabutylammonium bromide (TBAB) addition to the dispersions show that already small concentrations of added TBAB drastically decrease the electrostatic forces between colloidal particles. However, small, non-negligible contact potentials remain even at the highest TBAB concentrations added.

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Marcel Rudolf, Andreas Zumbusch. 2024-01-10. Temporal evolution of interparticle potentials of PMMA colloids in CHB/decaline. https://arxiv.org/abs/2401.05040

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