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arXiv · 2401.13519

Wave-graphene: a full-auxetic carbon semiconductor with high flexibility and optical UV absorption

Linfeng Yu·Yi Zhang·Jianzhou Lin·Kexin Dong·Xiong Zheng·Zhenzhen Qin·Guangzhao Qin
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Abstract

The abundant bonding possibilities of Carbon stimulate the design of numerous carbon allotropes, promising the foundation for exploring structure-functionality relationships. Herein, utilizing the space bending strategy, we successfully engineered a two-dimensional carbon allotrope with pure sp2 hybridization, named "Wave-graphene" from the unique wave-like ripple structure. The novel Wave-graphene exhibits full-auxetic behavior due to anisotropic mechanical response, possessing both negative and zero Poisson's ratios. The fundamental mechanism can be attributed to the fact that highly buckled out-of-plane structures lead to anisotropic responses of in-plane nonlinear interactions, which further lead to anisotropy of lattice vibrations. In addition, Wave-graphene is found having quasi-direct wide bandgap of 2.01 eV, the excellent optical transparency and the high flexibility. The successful design of Wave-graphene with excellent outstanding multifunctional properties shows that the utilization of space bending strategies can provide more degrees of freedom for designing novel materials, further enriching the carbon material family and supplementing its versatility.

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Linfeng Yu, Yi Zhang, Jianzhou Lin, Kexin Dong, Xiong Zheng, Zhenzhen Qin, Guangzhao Qin. 2024-01-24. Wave-graphene: a full-auxetic carbon semiconductor with high flexibility and optical UV absorption. https://arxiv.org/abs/2401.13519

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