SearcharxivSearch

arXiv · 2401.14537

The CIPM list "Recommended values of standard frequencies": 2021 update

Abstract

This paper gives a detailed account of the analysis underpinning the 2021 update to the list of standard reference frequency values recommended by the International Committee for Weights and Measures (CIPM). This update focused on a subset of atomic transitions that are secondary representations of the second (SRS) or considered as potential SRS. As in previous updates in 2015 and 2017, methods for analysing over-determined data sets were applied to make optimum use of the worldwide body of published clock comparison data. To ensure that these methods were robust, three independent calculations were performed using two different algorithms. The 2021 update differed from previous updates in taking detailed account of correlations among the input data, a step shown to be important in deriving unbiased frequency values and avoiding underestimation of their uncertainties. It also differed in the procedures used to assess input data and to assign uncertainties to the recommended frequency values, with previous practice being adapted to produce a fully consistent output data set consisting of frequency ratio values as well as absolute frequencies. These changes are significant in the context of an anticipated redefinition of the second in terms of an optical transition or transitions, since optical frequency ratio measurements will be critical for verifying the international consistency of optical clocks prior to the redefinition. In the meantime, the reduced uncertainties for optical SRS resulting from this analysis significantly increases the weight that secondary frequency standards based on these transitions can have in the steering of International Atomic Time (TAI).

Explore related subjects

Keep this discovery

BibTeXRIS

H S Margolis, G Panfilo, G Petit, C Oates, T Ido, S Bize. 2024-01-25. The CIPM list "Recommended values of standard frequencies": 2021 update. https://arxiv.org/abs/2401.14537

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Delay-engineered dynamical phases in a programmable non-Markovian spin oscillator

Non-Markovian dynamics offer a new route towards engineering non-equilibrium matter, where memory and feedback act as programmable resources for controlling order in time. Here we report the realization of a non-Markovian spin oscillator in a hot vapour $^{129}$Xe-Cs co-magnetometer with programmable feedback delay and gain. By tuning these parameters, we observe a hierarchy of dynamical phases, including time-crystalline response, nonlinear bifurcations, and frequency-comb formation. The measured spectra and phase boundaries are captured by linear stability analysis of delayed Bloch equations, revealing these phenomena as different manifestations of the same memory-induced instability structure. These results establish time-delayed feedback as a powerful strategy for controlling non-equilibrium phases, enabling quantum sensing, frequency referencing, and synchronization within a single spin-based platform.

physics.atom-ph

Non-stick vacuum wall collisions with a laser-coolable molecule

Molecular species that are suitable for direct laser cooling are typically considered lost or destroyed if they collide with an ambient temperature vacuum wall. Here, we study surface collisions with aluminum monofluoride (AlF), a laser-coolable molecule that survives this process with unusually high probability. We detect the outgoing AlF molecules from a single wall collision via Doppler-sensitive laser-induced fluorescence spectroscopy, using incoming supersonic (pulsed) and thermochemical (continuous) molecular beams. The angular, velocity and rovibrational level distributions of the outgoing molecules show near-complete thermalisation to the wall in a single collision event. We determine an upper limit to the surface residence time of about 5$~\mu$s, and by monitoring the decay in density of pulses of molecules loaded into a small storage volume, we deduce the surface sticking probability for different materials. For a siloxane-coated metallic surface, the sticking probability of AlF is about 0.015, allowing us to accumulate molecules from the thermochemical source into an ambient temperature storage vessel at densities near $10^{8}~$cm$^{-3}$. This provides a route to compact, portable traps for neutral molecules.

physics.atom-ph

Kinetic modeling of molecular beam formation in a cryogenic buffer-gas cell

Cryogenic buffer-gas cells are widely used to produce cold molecular beams, but the microscopic dynamics governing beam formation remain challenging to model. Here we present fully kinetic simulations of a cryogenic buffer-gas cell using the Direct Simulation Monte Carlo method implemented in the PICLas framework, treating the buffer gas and ablated molecules within a single unified model. We capture characteristic features of cryogenic buffer-gas sources, including plume cooling, directed transport toward the aperture, and the formation of a slow molecular beam, while also resolving energy transfer from the hot ablation plume to the helium buffer gas that is inaccessible to existing approaches relying on the background-gas approximation. Our results demonstrate that fully kinetic simulations can provide detailed insights into buffer-gas cell dynamics and open a route toward a systematic optimization of such sources.

physics.atom-ph