Structure determination of alkali trimers on helium nanodroplets through laser-induced Coulomb explosion

Abstract

Alkali trimers, Ak$_3$, located on the surface of He nanodroplets are triply ionized following multiphoton absorption from an intense femtosecond laser pulse leading to fragmentation into three correlated Ak$^+$ ions. Combining the information from three-fold covariance analysis of the emission direction of the fragment ions and from their kinetic energy distributions $P(E_{\text{kin}})$, we find that Na$_3$, K$_3$, and Rb$_3$ have an equilateral triangular structure, corresponding to that of the lowest-lying quartet state $^{4}\mathrm{A}_{2}'$, and determine the equilibrium bond distance $R_\text{eq}$(Na$_3$) = 4.65 $\pm$ 0.15 {\AA}, $R_\text{eq}$(K$_3$) = 5.03 $\pm$ 0.18 {\AA}, and $R_\text{eq}$(Rb$_3$) = 5.45 $\pm$ 0.22 {\AA}. For K$_3$ and Rb$_3$ these values agree well with existing theoretical calculations, while for Na$_3$ the value is 0.2-0.3 {\AA} larger than the existing theoretical results. The discrepancy is ascribed to a minor internuclear motion of Na$_3$ during the ionization process. Also, we determine the distribution of internuclear distances $P(R)$ under the assumption of fixed bond angles. The results are compared to the square of the internuclear wave function $|\Psi(R)|^2$.