Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · 2407.15958

The 2024 KIDA network for interstellar chemistry

V. Wakelam·P. Gratier·J. -C. Loison·K. M. Hickson·J. Penguen·A. Mechineau
View original source ↗Read source document ↗Export metadata ↓

Abstract

The study of the chemical composition of the interstellar medium (ISM) requires a strong synergy between laboratory astrophysics, modeling, and observations. In particular, astrochemical models have been developed for decades now and include an increasing number of processes studied in the laboratory or theoretically. These models follow the chemistry both in the gas phase and at the surface of interstellar grains. Since 2012, we have provided complete gas-phase chemical networks for astrochemical codes that can be used to model various environments of the ISM. Our aim is to introduce the new up-to-date astrochemical network kida.uva.2024 together with the ice chemical network and the fortran code to compute time dependent compositions of the gas, the ice surface, and the ice mantles under physical conditions relevant for the ISM. The gas-phase chemical reactions, as well as associated rate coefficients, included in kida.uva.2024 were carefully selected from the KIDA online database and represent the most recent values. The model predictions for cold core conditions and for when considering only gas-phase processes were computed as a function of time and compared to the predictions obtained with the previous version, kida.uva.2014. In addition, key chemical reactions were identified. The model predictions, including both gas and surface processes, were compared to the molecular abundances as observed in the cold core TMC1-CP. Many gas-phase reactions were revised or added to produce kida.uva.2024. The new model predictions are different by several orders of magnitude for some species. The agreement of this new model with observations in TMC-1 (CP) is, however, similar to the one obtained with the previous network.

Explore related subjects

astro-ph.GA

Keep this discovery

BibTeXRIS

V. Wakelam, P. Gratier, J. -C. Loison, K. M. Hickson, J. Penguen, A. Mechineau. 2024-07-22. The 2024 KIDA network for interstellar chemistry. https://arxiv.org/abs/2407.15958

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Fast Dynamical Modelling of Milky Way Globular Clusters -- II. Impacts of Black Hole Prescriptions

The populations of stellar-mass black holes (BHs) in globular clusters (GCs) play a key role in their dynamical evolution, however the mechanisms surrounding their formation and retention are uncertain. In this work, we extend the analysis of Paper I by fitting coupled rapid cluster evolution and multimass equilibrium models to a large sample of Milky Way GCs, under a variety of prescriptions for stellar evolution, BH formation and supernovae (SN) natal kicks. We explore the impacts of adopting SSE or PARSEC (through SEVN) prescriptions for BH initial-final mass relations, the rapid or delayed SN fallback mechanisms, and an ad hoc grid of kick strengths ejecting between 40 and 80 per cent of all BHs formed. All models reproduce the same present-day conditions despite starting from notably different initial BH populations, due to the correlation found between the initial cluster densities and initial BH mass fractions. A linear relationship is found between the (log) initial half-mass density and the initial BH mass fraction, with the SEVN models resulting in median densities ($\rho_{h,0} \sim 10^{7.2\pm1.1}\,{M_\odot pc^{-3}}$) nearly an order of magnitude higher than those of SSE ($\rho_{h,0} \sim 10^{6.4\pm0.9}\,{M_\odot pc^{-3}}$). We also find that both the bottom-light initial mass functions and the present-day BH mass fractions previously inferred are relatively robust against the stellar evolution models and natal kick prescriptions assumed. Finally, we discuss the implications of these results on the expected numbers and properties of dynamical binary-BH mergers, and the growth of intermediate-mass BHs.

astro-ph.GA↗
arXiv2026

SPURS: An Ultra-deep View Inside the Compact, Nitrogen-Enriched Nuclei of Little Red Dots

We present the first ultra-deep rest-UV spectroscopy of four UV-bright Little Red Dots (LRDs), obtained from the SPURS Cycle 4 Large Program. The spectra reveal broad CIV (FWHM $\approx2700-2800$ km s$^{-1}$) in two LRDs, alongside narrow-line densities elevated above star-forming galaxies ($n_e\sim10^4-10^5$ cm$^{-3}$, reaching $10^6$ cm$^{-3}$ in the most extreme source) and nitrogen-enhancements in all four LRDs. We detect broad HeII emission (FWHM $\approx930$ km s$^{-1}$) in one LRD, and two others with fast P-Cygni absorption ($\gtrsim2200$ km s$^{-1}$). Strong interstellar absorption lines and Ly$\alpha$ damping wings reveal the UV continuum is deeply embedded in neutral gas ($N_{\rm HI}\gtrsim10^{22}$ cm$^{-2}$) in all four LRDs. Detections of fluorescent FeII and OI emission and fine-structure absorption indicate this gas lies close to the UV-emitting region. In archival $z>4$ samples, we find nitrogen and strong CIII] emission are significantly more common in LRDs than in the galaxy population. The transmission of broad CIV, tracing the broad-line region or cocoon, depends on rest-optical color within our sample, consistent with an orientation-dependent picture in which bluer, less obscured sightlines offer a more direct, polar view of the central engine and its outflows. We find several potential signatures of very massive stars, whose winds may contribute to nitrogen enhancement. We investigate other abundance patterns expected from supermassive stars but our results are inconclusive. Our results place the UV-emitting region within $\lesssim8$ pc of the LRD nucleus, consistent with an actively assembling nuclear star cluster. Dynamical interactions in this extremely dense environment, including tidal disruption of stars, may explain the high incidence of nitrogen enhancements in LRDs.

astro-ph.GA↗
arXiv2026

Nitrogen-Loud Quasars from the Dark Energy Spectroscopic Instrument. I. Sample Selection and Basic Properties

We present the largest sample to date of nitrogen-loud (N-loud) quasars with strong broad N IV] $\lambda1486$ and/or N III] $\lambda1750$ emission lines over the redshift range $1.6 < z < 4.3$, selected from the Dark Energy Spectroscopic Instrument (DESI) Data Release 1. The final sample contains 1,993 N-loud quasars, corresponding to about 1.2% of the parent quasar sample. The $L_{1450}$ distribution of the N-loud quasars is broadly similar to that of the DESI parent sample, but their redshift distribution is distinct, with a stronger concentration around $z \sim 2.5$--3. Their composite spectrum displays a broadly similar UV continuum shape to that of the parent quasars, while showing significantly enhanced broad nitrogen emission features, including N V, N IV], and N III]. Other metal emission features also show a moderate enhancement. Relative to a control sample matched in redshift and UV continuum luminosity, the N-loud quasars show systematically narrower broad C IV and Mg II emission lines, lower single-epoch virial black hole masses, and higher Eddington ratios, suggesting that N-loud quasars may preferentially appear during a relatively rapid black hole accretion phase. The radio-loud fraction is 10.1%, with the highest fraction among objects exhibiting both N III] and N IV] emission. The catalog provides a statistical baseline for future studies of nitrogen enhancement and its physical origin.

astro-ph.GA↗