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arXiv · 2408.12506

Effect of Frequency-Dependent Viscosity on Molecular Friction in Liquids

Henrik Kiefer·Domenico Vitali·Benjamin A. Dalton·Laura Scalfi·Roland R. Netz
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Abstract

The relation between the frequency-dependent friction of a molecule in a liquid and the hydrodynamic properties of the liquid is fundamental for molecular dynamics. We investigate this connection for a water molecule moving in liquid water using all-atomistic molecular dynamics simulations and linear hydrodynamic theory. We analytically calculate the frequency-dependent friction of a sphere with finite surface slip moving in a viscoelastic compressible fluid by solving the linear transient Stokes equation, including frequency-dependent shear and volume viscosities, both determined from MD simulations of bulk liquid water. We also determine the frequency-dependent friction of a single water molecule moving in liquid water, as defined by the generalized Langevin equation from MD simulation trajectories. By fitting the effective sphere radius and the slip length, the frequency-dependent friction and velocity autocorrelation function from the transient Stokes equation and simulations quantitatively agree. This shows that the transient Stokes equation accurately describes the important features of the frequency-dependent friction of a single water molecule in liquid water and thus applies down to molecular length and time scales, provided accurate frequency-dependent viscosities are used. The frequency dependence of the shear viscosity of liquid water requires careful consideration of hydrodynamic finite-size effects to observe the asymptotic hydrodynamic power-law tail. In contrast, for a methane molecule moving in water, the frequency-dependent friction cannot be predicted based on a homogeneous model, which suggests, supported by the extraction of a frequency-dependent surface-slip profile, that a methane molecule is surrounded by a finite-thickness hydration layer with viscoelastic properties that are significantly different from bulk water.

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Henrik Kiefer, Domenico Vitali, Benjamin A. Dalton, Laura Scalfi, Roland R. Netz. 2024-08-22. Effect of Frequency-Dependent Viscosity on Molecular Friction in Liquids. https://arxiv.org/abs/2408.12506

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