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arXiv · 2410.07479

Chiral effects at the metal center in Fe(III) spin crossover coordination salts

M Zaid Zaz·Wai Kiat Chin·Gauthami Viswan·Arjun Subedi·Esha Mishra·Kayleigh A McElveen·Binny Tamang·David Shapiro·Alpha T NDiaye·Rebecca Y Lai·Peter A Dowben
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Abstract

Evidence of chirality was observed at the Fe metal center in Fe(III) spin crossover coordination salts [Fe(qsal)2][ Ni(dmit)2] and [Fe(qsal)2](TCNQ)2 from X-ray absorption spectroscopy at the Fe 2p3/2 core threshold. This indicates the formation of chiral domains that influence the octahedral coordination on the Fe core.

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M Zaid Zaz, Wai Kiat Chin, Gauthami Viswan, Arjun Subedi, Esha Mishra, Kayleigh A McElveen, Binny Tamang, David Shapiro, Alpha T NDiaye, Rebecca Y Lai, Peter A Dowben. 2024-10-09. Chiral effects at the metal center in Fe(III) spin crossover coordination salts. https://arxiv.org/abs/2410.07479

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