arXiv · 2410.24180
Confined density of states, quantum concentration, and electron degeneracy pressure in low-dimensional systems
Abstract
We present a simple derivation of the density of states (DOS) in confined nanomaterials. While previous studies often apply a heuristic $L^{3-d}$ confinement factor to bulk DOS expressions, we show that this factor arises naturally from a consistent quantum-mechanical treatment of quasi-dimensional systems. Using a Fermi gas model, we calculate carrier concentration in across different dimensions and introduce the concept of quantum concentration $n_Q$ as a statistical threshold for quantum confinement effect. We further demonstrate that the electron degeneracy pressure -- scaling with $n^{(d+2)/d}$ -- provides a thermodynamic explanation for carrier enhancement under quantum confinement. Our results clarify the origin of DOS modification and provide insights for low-dimensional materials.
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Benedick Andrade, Rayda Gammag. 2024-10-31. Confined density of states, quantum concentration, and electron degeneracy pressure in low-dimensional systems. https://doi.org/10.1088/1402-4896%2Fae3fd8
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