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arXiv · 2411.06072

Magnetic properties of frustrated spin-$\frac{1}{2}$ capped-kagome antiferromagnet (CsBr)Cu$_5$V$_2$O$_{10}$

S. Guchhait·D. V. Ambika·S. Mohanty·Y. Furukawa·R. Nath
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Abstract

The structural and magnetic properties of a spin-$\frac{1}{2}$ averievite (CsBr)Cu$_5$V$_2$O$_{10}$ are investigated by means of temperature-dependent x-ray diffraction, magnetization, heat capacity, and $^{51}$V nuclear magnetic resonance (NMR) measurements. The crystal structure (trigonal, $P\bar{3}$) features a frustrated capped-kagome lattice of the magnetic Cu$^{2+}$ ions. Magnetic susceptibility analysis indicates a large Curie-Weiss temperature of $\theta_{\rm CW} \simeq-175$ K. Heat capacity signals the onset of a magnetic long-range-order (LRO) at $T_{\rm N}\simeq 21.5$ K at zero magnetic field due to the presence of significant inter-planer coupling in this system. The magnetic LRO below 27 K is further evident from the drastic change in the $^{51}$V NMR signal intensity and rapid enhancement in the $^{51}$V spin-lattice relaxation rate in a magnetic field of 6.3 T. The frustration index $f=|\theta_{\rm CW}|/T_{\rm N} \simeq 8$ ascertains strong magnetic frustration in this compound. From the high-temperature value of the $^{51}$V NMR spin-lattice relaxation rate, the leading antiferromagnetic exchange interaction between the Cu$^{2+}$ ions is calculated to be $J/k_{\rm B}\simeq 136$ K.

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S. Guchhait, D. V. Ambika, S. Mohanty, Y. Furukawa, R. Nath. 2024-11-09. Magnetic properties of frustrated spin-$\frac{1}{2}$ capped-kagome antiferromagnet (CsBr)Cu$_5$V$_2$O$_{10}$. https://arxiv.org/abs/2411.06072

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