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arXiv · 2502.03841

Dendrite Suppression in Zn Batteries Through Hetero-Epitaxial Residual Stresses Shield

Musanna Galib·Amardeep Amardeep·Jian Liu·Mauricio Ponga
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Abstract

Dendrite formation is a long-standing problem for the commercial application of aqueous zinc (Zn)-ion batteries (AZIB). Here, we investigate the effect of hetero-epitaxial residual stresses due to layered coatings on dendrite suppression. We found that atomic and molecular layered coatings can substantially reduce dendritic growth in AZIB by providing shielding due to residual stresses, even at single and a few layers of coatings. Through a combined experimental and numerical approach, we demonstrate that the residual stresses developed due to the coating of the Zn anodes significantly reduced the chemical potential polarization around dendrite embryos, forcing the deposition of zinc in the regions adjacent to the protuberances. This, in turn, results in a slower rate of dendritic growth, and eventually, dendrite suppression. The fundamental understanding of the effect of residual stresses due to coatings demonstrated herein can be extended to various metal anode batteries such as Li or Na.

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Musanna Galib, Amardeep Amardeep, Jian Liu, Mauricio Ponga. 2025-02-06. Dendrite Suppression in Zn Batteries Through Hetero-Epitaxial Residual Stresses Shield. https://arxiv.org/abs/2502.03841

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