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arXiv · 2503.15912

Normal and inverse magnetocaloric effects in structurally disordered Laves phase Y$_{1-x}$Gd$_{x}$Co$_{2}$ (0 $\leq$ x $\leq$ 1) compounds

Natalia Pierunek·Zbigniew Śniadecki·Mirosław Werwiński·Bartosz Wasilewski·Victorino Franco·Bogdan Idzikowski
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Abstract

Magnetic and magnetocaloric properties of Y$_{1-x}$Gd$_{x}$Co$_{2}$ compounds, where x = 0.2, 0.4, 0.6, 0.8 and 1.0, were investigated experimentally and theoretically. Crystal structures were characterized by X-ray diffraction (Rietveld analysis) and investigated samples possess the MgCu$_{2}$-type single phase with Fd-3m space group. Melt-spinning process introduced a chemical and topological disorder, which directly affected the magnetic properties. Refrigerant capacity (RC), strictly connected to the full width at half maximum $\delta$TFWHM of the $\Delta$S$_M$(T) curve and the maximum of magnetic entropy changes $\Delta$S$_{Mpk}$(T)(T,$\Delta$H), increases from 29 to 148 J/kg with replacement of Y by Gd atoms from x = 0.2 to x = 0.8. RC and $\delta$TFWHM indicate the presence of disorder. Temperature dependences of magnetic entropy change $\Delta$S$_M$(T,$\Delta$H) and RC were measured in as-quenched and annealed state for Y$_{0.4}$Gd$_{0.6}$Co$_{2}$. This particular composition was chosen for detailed investigation mainly due to its Curie point (T$_C$ = 282 K), which is close to the room temperature. After isothermal annealing ($\tau_a$ = 60 min, Ta = 700$^o$C) RC decreased from 122 to 104 J/kg, which clearly indicates the homogenization of the heat treated sample. Furthermore, observed inverse magnetocaloric effect is associated with the presence of antiferromagnetically coupled Gd and Co magnetic moments. The phase transition temperature increases with increasing Gd content from 74 to 407 K for Y$_{0.8}$Gd$_{0.2}$Co$_{2}$ and GdCo2, respectively. Within the FPLO-LDA DFT method, the non-magnetic ground state for YCo$_{2}$ and the magnetic ground state for GdCo$_{2}$ are predicted in agreement with experiment. The dependence of calculated total and species-resolved magnetic moments on Gd concentration reasonably agrees with available experimental data.

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Natalia Pierunek, Zbigniew Śniadecki, Mirosław Werwiński, Bartosz Wasilewski, Victorino Franco, Bogdan Idzikowski. 2025-03-20. Normal and inverse magnetocaloric effects in structurally disordered Laves phase Y$_{1-x}$Gd$_{x}$Co$_{2}$ (0 $\leq$ x $\leq$ 1) compounds. https://doi.org/10.1016/j.jallcom.2017.01.181

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