Leveraging MMW-MMW Double Resonance Spectroscopy to Understand the Pure Rotational Spectrum of Glycidaldehyde and 17 of Its Vibrationally Excited States

Abstract

Broadband measurements of glycidaldehyde in the frequency ranges 75-170 and 500-750 GHz were recorded to extend previous analyses of its pure rotational spectrum in the microwave region. The rotational parameters of the ground vibrational states for the main isotopologue and the three singly 13C-substituted isotopologues were considerably improved, and additional higher-order parameters were determined. To identify new vibrationally excited states in the dense and convoluted spectrum, an updated version of the double-modulation double-resonance spectroscopy technique was used. Connecting transitions with a shared energy level into series and expanding these via Loomis-Wood plots proved to be a powerful method, which allowed the identification of 11 new vibrationally excited states in addition to the already known aldehyde torsions, v21 = 1 to v21 = 6. Interactions between several vibrational states were observed, and three interacting systems were treated successfully. Rotational transitions of glycidaldehyde were searched for in the imaging spectral line survey ReMoCA obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) toward the high-mass star-forming region Sgr B2(N). The observed spectra were modeled under the assumption of local thermodynamic equilibrium (LTE). Glycidaldehyde, an oxirane derivative, was not detected toward Sgr B2(N2b). The upper limit on its column density implies that it is at least six times less abundant than oxirane in this source.