Lattice Quantum Geometry Controlling 118 K Multigap Superconductivity in Heavily Overdoped CuBa2Ca3Cu4O10+d

Abstract

Synchrotron X-ray diffraction has been used to study the thermal structure evolution in CuBa2Ca3Cu4O10+d (Cu1234), a superconductor which exhibits a high critical temperature (Tc 118 K), high critical current density and large upper critical magnetic field. The lattice geometry at nanoscale of this cuprate belongs to the class of natural heterostructures at atomic limit like the artificial high Tc superlattices made of interface space charge in Mott insulator units intercalated by metal units. Temperature-dependent lattice parameters reveal a distinct structural transition at TC characterized by a drop of the c-axis and in plane Cu-O negative thermal expansion below TC. These results provide clear evidence of lattice reorganization associated with the chemical potential changes due to the opening of multiple superconducting gaps. Additionally, evidence for oxygen defects rearrangement is observed at temperatures above 200 K. We construct a phase diagram correlating temperature, the c/a axis ratio, and in plane Cu-O strain, identifying regions associated with gaps opening and oxygen rearrangement. These findings provide new insights into how lattice geometry control superconductivity to inform the material design of advanced nanoscale superconducting artificial quantum heterostructures.