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arXiv · 2505.14248

Enhanced 133cs Triple-Quantum Excitation in Solid-State NMR of Cs-Bearing Zeolites

Noy Vaisleib·Michal Arbel-Haddad·Amir Goldbourt
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Abstract

Geopolymers are aluminosilicate materials that exhibit effective immobilization properties for low-level radioactive nuclear waste, and more specifically for the immobilization of radioactive cesium. The identification of the cesium-binding sites and their distribution between the different phases making up the geopolymeric matrix can be obtained using solid-state NMR measurements of the quadrupolar spin 133Cs, which is a surrogate for the radioactive cesium species present in nuclear waste streams. For quadrupolar nuclei, acquiring two-dimensional multiple-quantum experiments allows the acquisition of more dispersed spectra when multiple sites overlap. However, 133Cs has a spin-7/2 and one of the smallest quadrupole moments, making multiple-quantum excitation highly challenging. In this work we present pulse schemes that enhance the excitation efficiency of 133Cs triple quantum coherences by a factor of ~2 with respect to a two-pulse excitation scheme. The improved schemes were developed by using numerical simulation and verified experimentally by applying one and two-dimensional triple-quantum solid-state NMR experiments to a mixture of cesium-exchanged hydrated zeolites A and X, which possess dynamically averaged small quadrupolar coupling constants in the order of 10 kHz.

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Noy Vaisleib, Michal Arbel-Haddad, Amir Goldbourt. 2025-05-20. Enhanced 133cs Triple-Quantum Excitation in Solid-State NMR of Cs-Bearing Zeolites. https://arxiv.org/abs/2505.14248

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