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arXiv · 2506.14622

Liquid-gas state regularities as a manifestation of global isomorphism with the Ising model

L. A. Bulavin·V. L. Kulinskii·A. M. Katts·A. M. Maslechko
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Abstract

Liquid-gas equilibrium is considered using the global isomorphism with the Ising-like (lattice gas) model. Such an approach assumes the existence of the order parameter in terms of which the symmetry of binodal is restored not only in the vicinity of the critical point (critical isomorphism) but also globally in the whole coexistence region. We show how the empirical law of the rectilinear density diameter of the liquid-gas binodal allows us to derive a rather simple form of the isomorphism transformation between the fluid and lattice gas model of Ising-type. The relations for critical parameters which follow from such isomorphism are tested on a variety of fluid systems, both real and model ones. Moreover, we consider the phase equilibrium in polymer solutions and the Flory $\theta$-point as the extreme state of such equilibrium within our approach. The most crucial testing in 2D case is using the Onsager exact solution of the Ising model, and we represent the results of our approach to the calculation of critical point parameters of monolayers for noble gases and the surface tension.

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L. A. Bulavin, V. L. Kulinskii, A. M. Katts, A. M. Maslechko. 2025-06-17. Liquid-gas state regularities as a manifestation of global isomorphism with the Ising model. https://doi.org/10.5488/cmp.28.23603

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