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arXiv · 2508.01734

Photoinduced Low Spin to High Spin Transition in a [2x2] Fe(II) Metallogrid: Diode Laser-Pumped Photocrystallography at the P11 Beamline in PETRA III, DESY

Krishnayan Basuroy·Jose de Jesus Velazquez-Garcia·Sreeju Sreekantan Nair Lalithambika·Argha Barman·Torben Reuss·Guillaume Pompidor·Alexander Grebentsov·Önder Akçaalan·Simone Techert
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Abstract

We report on the photoinduced spin crossover (SCO) transition from a 2HS-2LS to a 3HS-1LS state in a [2x2] Fe(II) metallogrid complex using molecular crystals with static photocrystallography at a first ever attempt in the beamline P11 of the PETRA III synchrotron, DESY. A class 3B diode laser was used to induce the transition under controlled irradiation conditions. Structural characterization was achieved through single-crystal X-ray diffraction (SCXRD) measurements post-irradiation, revealing significant changes in average Fe-N distances, consistent with SCO behavior. Our experimental setup enables precise alignment necessary for photo-excitation using a class 3B diode laser along with a compact focusing optics. The longest dimension of the combined setup of the diode head and the focusing optics is not more than 32cm. The setup showcasing the utility of a compact diode laser system which can even be conveniently used in synchrotron-based pump-probe photocrystallography experiments for a wide range of molecular crystals.

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Krishnayan Basuroy, Jose de Jesus Velazquez-Garcia, Sreeju Sreekantan Nair Lalithambika, Argha Barman, Torben Reuss, Guillaume Pompidor, Alexander Grebentsov, Önder Akçaalan, Simone Techert. 2025-08-03. Photoinduced Low Spin to High Spin Transition in a [2x2] Fe(II) Metallogrid: Diode Laser-Pumped Photocrystallography at the P11 Beamline in PETRA III, DESY. https://arxiv.org/abs/2508.01734

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