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arXiv · 2509.01273

Ionization/dissociation-driven first order phase transitions: on a new class of first order phase transitions

Genri Norman·Ilnur Saitov
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Abstract

In this work, we compare various models for describing the phase transition of the fluid hydrogen into a conducting state, including both chemical models of plasma and first-principle simulations within the framework of the density functional theory (DFT). The comparison of the results indicates the plasma nature of the phase transition in warm dense hydrogen. We propose a concept of a new class of first-order phase transitions: ionization or dissociation-driven phase transitions, with which the plasma phase transition in fluid hydrogen can be associated.

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Genri Norman, Ilnur Saitov. 2025-09-01. Ionization/dissociation-driven first order phase transitions: on a new class of first order phase transitions. https://arxiv.org/abs/2509.01273

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