Volatile-bearing mineral atmospheres of hot rocky exoplanets as probes of interior state and composition

Abstract

The atmospheres of hot rocky exoplanets (HREs), should they persist, are products of interactions with underlying magma oceans. Spectra collected by the James Webb Space Telescope (JWST) hint at a CO/CO$_2$-rich atmosphere on the HRE 55 Cancri e, indicative of such a process. Here, we aim to identify diagnostic features that can be used to infer the composition and geochemical state of HREs. We construct a coupled atmosphere-interior model that computes the equilibrium gas speciation in the atmosphere in the system Si-Mg-Fe-O-C-H-S-N-He. The model accounts for both the equilibrium vaporisation of mineral gases and the partitioning of volatile species between the magma ocean and atmosphere. Using a fiducial planet with the properties of 55 Cancri e, we explore a parameter space that spans volatile mass fractions from 0.1 to 10 times that of the Earth, solar- to Earth-like metallicities, and 12 orders of magnitude in oxygen fugacity fO$_2$. We find fO$_2$ to be the major control of the shape of emission and transmission features. The presence of species such as SO$_2$ and the relative intensities of H$_2$O and CO$_2$ features allow to distinguish the origin of the gas, accreted or outgassed, while the atmospheric mass is more challenging to constrain. Inflated HREs, whose densities are compatible with a nebular atmosphere are rare, but a viable explanation for the planet TOI-1408 c. The majority of HREs, including 55 Cancri e, are too dense to be dominated by H$_2$-rich nebular gas yet too puffy for an Earth-like volatile budget, implying modest atmospheres of mixed heritage that are degenerate in fO$_2$, volatile mass and composition. The MIRI observation of 55 Cancri e disfavours oxidised Earth-like and reduced primoridal atmospheres alike, while the NIRCam data remain inconclusive. Future observations at wavelengths beyond 8 $\mu$m are key to discerning between potential scenarios.