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arXiv · 2510.24552

Approaching the Thermodynamic Limit of an Ideal Gas

Prabal Adhikari·Brian Tiburzi·Sona Baghiyan
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Abstract

For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles. While such correlations have a vanishing effect in the thermodynamic limit, examining them is beneficial for a sharper understanding of how the limit is attained. We contrast a classical and a quantum model of particle-wall correlations within the canonical ensemble.

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Prabal Adhikari, Brian Tiburzi, Sona Baghiyan. 2025-10-28. Approaching the Thermodynamic Limit of an Ideal Gas. https://doi.org/10.1119/5.0200913

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