Freezing and ice aging dynamics in saline water under natural convection

Abstract

Understanding the coupled dynamics of liquid-solid phase change and fluid flows is crucial in a wide range of geophysical and industrial applications. When freezing occurs in saline water, the newly formed ice is mushy, with a porous structure that traps the brine within the ice. In this work, which combines experiments and theoretical analyses, we investigate the long-term evolution of saline ice, comprehensively accounting for the coupled dynamics of multiscale fluid flow, heat and mass transfer, and phase change. We show that in a closed convective system the rapid formation of a mushy ice layer is followed by desalination (i.e, the expulsion of salt from the ice) processes that might lead to a slow asymptotic decrease of the ice thickness. Desalination of mushy ice reduces its porosity, which alters the dynamic thermal equilibrium and ice thickness by weakening buoyancy-driven convection within the mushy layer. In turn, changes in brine convection and ice thickness affect the further desalination of the ice. The long-term dynamics of the system can be accurately predicted by a one-dimensional model based on appropriate parameterizations of global heat and mass transfer properties. Furthermore, within the same theoretical model we explore the ice dynamics across a broader parameter space. Our findings advance the understanding of the coupled phase-change physics of saline solutions in the presence of convective fluid flows and provide a basis for explaining and predicting real-world phenomena such as the aging of sea ice.