Speciation and hydration forces in sodium carbonate/bicarbonate aqueous solutions nanoconfined between mica sheets

Daria Turculet; Shurui Miao; Kieran Agg; Susan Perkin

Home/Archive/arXiv

arXiv · 2512.03904

Speciation and hydration forces in sodium carbonate/bicarbonate aqueous solutions nanoconfined between mica sheets

Daria Turculet·Shurui Miao·Kieran Agg·Susan Perkin

View original source ↗Read source document ↗Export metadata ↓

Abstract

The equilibrium between hydrated and hydrolysed forms of CO2 in water is central to a multitude of processes in geology, oceanography and biology. Chemistry of the carbonate system is well understood in bulk solution, however processes such as mineral weathering and biomineralisation frequently occur in nano-confined spaces where carbonate chemistry is less explored. For confined systems, the speciation equilibria are expected to tilt due to surface reactivity, electric fields and reduced configurational entropy. In this discussion paper we provide measurements of interaction force between negatively charged aluminosilicate (mica) sheets across aqueous carbonate/bicarbonate solutions confined to nanoscale films in equilibrium with a reservoir of the solution. By fitting the measurements to a Poisson-Boltzmann equation modified to account for charge regulation at the bounding walls, we discuss features of the bicarbonate speciation in confinement. We find that (i) the presence of bicarbonate in the bulk reservoir causes a repulsive excess pressure in the slit compared to pH-neutral salt solutions at the same concentration, arising from a higher (negative) effective charge on the mica surfaces; (ii) the electrostatic screening length is lower for solutions of Na2CO3 compared to NaHCO3 at the same bulk concentration, due to a shift in the speciation equilibria with pH and in accordance with Debye-H\"uckel theory; (iii) hydration forces are observed at distances below 2 nm with features of size 0.1 nm and 0.3 nm; this was reproducible across the various bicarbonate electrolytes studied, and contrasts with hydration forces of uniform step size measured in pH-neutral electrolytes.

Explore related subjects

cond-mat.soft

Keep this discovery

BibTeX RIS

Daria Turculet, Shurui Miao, Kieran Agg, Susan Perkin. 2025-12-03. Speciation and hydration forces in sodium carbonate/bicarbonate aqueous solutions nanoconfined between mica sheets. https://arxiv.org/abs/2512.03904

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Slow Dynamics and the Geometry of Jammed Packings

Saddle points in the energy landscape of granular packings dominate the discrete steepest descent dynamics and ultimately determine the path that an out of mechanical equilibrium packing will follow and the resulting stable minimum that it will find. The saddle points that ultimately determine the resulting minima tend to be low-index saddle points. For models with an analytic energy landscape, such as the $p$-spin model, the steepest descent minimization path is affected by higher-index saddle points, which pull the system towards saddle points of decreasing index before arriving at the minima. Here, we examine the steepest descent minimization path of granular packings and compare them to the $p$-spin model. We show that the granular packing steepest descent minimization paths act like their smooth energy landscape counterparts and get attracted by saddle points. The index versus time curves for all models follow a shifted, stretched exponential. We further show that the shape parameter for the granular packings is unchanged when the energy landscape is modified to become analytic (Gaussian potential in a harmonic well) or non-local (Mari-Krzakala-Kurchan). The $p$-spin, on the other hand, has a significantly larger shape parameter. The reason is not due to the dimensionality, packing fraction, nonanalyticity, or the locality of the Hamiltonian of the models. The exact reason for the discrepancy in the shape parameter is \st{still} an unsolved mystery.

cond-mat.soft↗

arXiv2026

A Phase-Field Study of Desiccation Crack Pattern Maturation under Drying-Wetting Cycles

The characteristic intersection angle of the desiccation crack relaxes from near \ang{90} toward \ang{120} under repeated drying--wetting cycles. However, the theoretical understanding of this relaxation is insufficient, especially the modeling of the drying--wetting cycles. Here we introduce a phase-field model of desiccation fracture, extending the model proposed in previous studies by adding crack healing and a scar effect left by past cracks. By repeating drying--wetting cycles in a finite element simulation, we find that the angle distribution develops a growing peak near \ang{120} as the cycle number increases, consistent with experiments. The standard deviation of the intersection angle from \ang{120} relaxes exponentially with a characteristic time of about 2.85 cycles. These results are consistent with experiments, except that the characteristic time is slightly smaller than the experimental value. Crack energy dominates the total energy and also relaxes exponentially with nearly the same characteristic cycle as the angle relaxation. This decay is driven mainly by a shortening of the effective crack length rather than a change in effective fracture toughness.

cond-mat.soft↗

arXiv2026

Kinetics of ferritin crystal formation and melting in acoustically levitated droplets

Understanding protein crystallization pathways is essential for controlling crystallization in structural biology, materials science, and pharmaceutical applications. Classical nucleation theory does not fully capture crystallization processes for several proteins, including ferritin. Here, we combine acoustic levitation with small- and wide-angle X-ray scattering (SAXS and WAXS) to monitor ferritin crystallization in evaporating aqueous polyethylene glycol (PEG) solutions. Acoustic levitation rapidly drives the droplets through a broad range of protein and polymer concentrations, enabling time-resolved measurements of crystallization during evaporation. The scattering data show that ferritin crystals form during evaporation and subsequently lose their crystalline order upon further dehydration. Varying the PEG molecular weight switches between distinct crystallization pathways: one dominated by attractive protein-protein interactions and another dominated by repulsive interactions and excluded-volume effects. Furthermore, we find that lower molecular weight PEG (1000 g/mol) suppresses the dehydration-induced loss of crystalline order observed for higher molecular weight PEG (6000 g/mol), providing a simple strategy for improving protein crystal stability.

cond-mat.soft↗