Compression-driven jamming in porous cohesive aggregates

Abstract

I investigate the compression-driven jamming behavior of two-dimensional porous aggregates composed of cohesive, frictionless disks. Three types of initial aggregates are prepared using different aggregation procedures, namely, reaction-limited aggregation (RLA), ballistic particle-cluster aggregation (BPCA), and diffusion-limited aggregation (DLA), to elucidate the influence of aggregate morphology. Using distinct-element-method simulations with a shrinking circular boundary, I numerically obtain the pressure as a function of the packing fraction $\phi$. For the densest RLA and the intermediate BPCA aggregates, a clear jamming transition is observed at a critical packing fraction $\phi_{\rm J}$, below which the pressure vanishes and above which a finite pressure emerges; the transition is less distinct for the most porous DLA aggregates. The jamming threshold depends on the initial structure and, when extrapolated to infinite system size, approaches $\phi_{\rm J} = 0.765 \pm 0.004$ for RLA, $0.727 \pm 0.004$ for BPCA, and $0.602 \pm 0.023$ for DLA, where the errors denote the standard error. Above $\phi_{\rm J}$, the pressure follows $P \approx A {( \phi - \phi_{\rm J} )}^{2}$, which implies that the bulk modulus $K$ of jammed aggregates is proportional to $\phi - \phi_{\rm J}$. Rigid-cluster analysis of jammed aggregates shows that the average coordination number within the largest rigid cluster increases linearly with $\phi - \phi_{\rm J}$. Taken together, these relations suggest that the elastic response of compressed porous aggregates is analogous to that of random spring networks.