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arXiv · 2603.08953

Ionic-instability induced color tuning in lead-based, mixed-halide perovskites

Anthony Ruth·Halyna Okrepka·Michele Vergari·Charlie Desnoyers·Minh Nguyen·Luca Gavioli·Prashant V. Kamat·Masaru Kuno
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Abstract

Contrary to conventional wisdom, intermediate photoluminescence energies can be stabilized in mixed-halide lead perovskites during photosegregation. These intermediate energies reside between those of the parent, mixed-halide alloy and fully photosegregated specimens. This demonstrates rudimentary color tuning and has practical implications for potential uses of mixed-halide perovskites in lighting applications. More fundamentally, such color tuning begs the question of how intermediate photosegregation energies arise and how they are kinetically stabilized. What follows is a study of the kinetics of terminal photosegregation energies under pulsed laser excitation. Through concerted continuous wave and pulsed laser photosegregation measurements, we develop a kinetic rationalization for how photosegregations repetition rate or duty cycle and peak fluence dependencies lead to intermediate, terminal photoluminescence energies. The developed model, in turn, explains prior observations of pulsed illumination photosegregation and offers potential insights into other, yet to be explained, phenomena such as spectral blueshifting under high intensity, pulsed illumination.

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Anthony Ruth, Halyna Okrepka, Michele Vergari, Charlie Desnoyers, Minh Nguyen, Luca Gavioli, Prashant V. Kamat, Masaru Kuno. 2026-03-09. Ionic-instability induced color tuning in lead-based, mixed-halide perovskites. https://arxiv.org/abs/2603.08953

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