Direct measurement of osmotic pressure and interparticle interactions in colloidal dispersions

Abstract

Colloidal dispersions are widely found in systems ranging from natural environments to industrial materials. Their macroscopic properties such as viscosity and light scattering depend on their dispersibility, which is characterized by interparticle interactions. Osmotic pressure is induced in a solution with a concentration gradient, in which dispersity is one of the major factors governing the behavior of solutes. Thus, examining the relationship between the interparticle interactions and osmotic pressure may reveal colloidal dispersive properties. Although measuring the osmotic pressure is useful to understand dispersion systems, osmotic pressure is usually extremely low, and only limited experimental methods are available. In this study, we demonstrate that both osmotic pressure and interparticle interactions can be measured within the same experimental system, an optical tweezer system. The directly measured pressure is consistent with both the Brownian dynamics simulation and theoretical results based on the effective hard-sphere model, both of which were calculated using the interparticle interactions directly measured in the experiment. This agreement demonstrates the applicability of the proposed technique for investigating dispersive properties based on particle-level interactions. The proposed technique enables bottom-up design of colloidal materials through particle-level modifications.