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arXiv · 2606.21219

Bose-Einstein Condensation of Three-Dimensional Exciton-Polaritons

Junhui Cao·Alexey Kavokin
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Abstract

We develop a band-structure-based theory of exciton-polaritons in a three-dimensional inverse-opal photonic crystal doped with semiconductor quantum dots. Starting from a symmetry-selected bright photonic branch near the photonic gap edge, we construct an exciton-photon Hamiltonian and obtain a lower-polariton band with a W-point global minimum and a nearby X-point van-Hove-enhanced density of states. We show that the W valleys determine the equilibrium Bose-Einstein condensation threshold, while the X-point saddle provides a finite excited-state capacity that renormalizes the critical temperature when the W-X offset is thermally accessible. By tuning the exciton resonance and the light-matter coupling, the relative W-X ordering can be reconstructed, leading to a strong variation of the critical temperature. We further formulate a momentum-resolved Boltzmann model for driven-dissipative kinetics. Under non-resonant pumping, reservoir feeding, radiative decay, and inter-sector relaxation can produce either W-dominated condensation, a mixed W-X regime, or an X-dominated nonequilibrium coherent state. Our results establish three-dimensional photonic-crystal polaritons as a platform where condensation is controlled not only by the band minimum but also by valley geometry, van-Hove-enhanced phase space, and relaxation pathways.

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Junhui Cao, Alexey Kavokin. 2026-06-19. Bose-Einstein Condensation of Three-Dimensional Exciton-Polaritons. https://arxiv.org/abs/2606.21219

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