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arXiv · 2606.22257

Magnetovolume effect in SrRu1-xCoxO3 (x = 0.0, 0.05)

Abstract

Polycrystalline SrRu1-xCoxO3 (x = 0.0, 0.05) and CaRuO3 were rapidly synthesized (< 1 hour) by microwave irradiation of oxide powders, and their magnetic, magnetoresistance, thermal expansion, and magnetostriction properties were investigated. The microwave-synthesised SrRuO3 exhibits a ferromagnetic transition at TC = 160 K, metallic-type resistivity, and negative magnetoresistance, with magnitudes comparable to those of a sample synthesized by conventional heating over 24 hours. Upon lowering the temperature from 300 K, the linear thermal expansion shows a transition from the usual contraction in the paramagnetic state to spontaneous expansion in the ferromagnetic state (invar-like effect). The application of an external magnetic field at a fixed temperature results in isotropic expansion of the length, implying a positive magnetovolume effect. The volume magnetostriction is 40 ppm at 10 K in a magnetic field of 50 kOe, and it reaches a maximum value of 60 ppm close to TC. The spontaneous thermal expansion is diminished in SrRu0.95Co0.05O3. While the magnetostriction is anisotropic at 10 K, the isotropic behaviour is recovered above 80 K, and the maximum value of the positive magnetovolume is comparable to that of the parent compound. Our results suggest that the magnetovolume effect in SrRu1-xCoxO3 is related to competition between robust tilting/rotation of RuO6 octahedra and spin-orbit interaction of the doped Co2+ ions

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BibTeXRIS

M. Manikandan, R. Mahendiran. 2026-06-20. Magnetovolume effect in SrRu1-xCoxO3 (x = 0.0, 0.05). https://arxiv.org/abs/2606.22257

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