Atmospheric evolution through outgassing and escape on young molten rocky exoplanets

Abstract

The earliest rocky planet atmospheres are shaped by competition between initial volatile inventories and atmospheric escape. On young magma ocean planets, outgassing competes with atmospheric escape, controlling volatile retention and atmospheric evolution. We investigate how atmospheric escape and replenishment via outgassing during magma ocean crystallization shape rocky planet atmospheres. We extend a coupled interior-atmosphere model to simulate rocky planet evolution during the magma ocean era by incorporating an energy-limited atmospheric escape module. Comparing radiative-convective and prescribed-convective atmospheres, we quantify how atmospheric energy transport affects escape. We explore a wide range of orbital separations, escape efficiencies, oxidation states, and initial volatile inventories to identify regimes where sustained magma-ocean outgassing or escape dominates. We estimate atmospheric loss and compositions for young rocky planets around Sun-like and M-dwarf stars over geologic timescales. Atmospheric escape shortens magma ocean lifetimes by weakening greenhouse insulation. Radiative-convective atmospheres reduce solidification timescales compared to purely convective cases. Volatile dissolution into the magma ocean interacts with escape to chemically fractionate the planetary volatile budget over time by retaining more soluble species. For Earth-mass planets, atmospheres survive if loss rates remain moderate. Mantle redox state remains a key control on retained atmospheric composition: high oxygen fugacity (fO2) yields heavier, H2O- and CO2-rich atmospheres, while low fO2 produces light, H2- or CO-dominated atmospheres, consistent with previous studies. Orbital separation, initial volatile inventory, and stellar type produce diverse evolutionary pathways, from bare rocky planets to magma oceans with thick atmospheres, ranging from H2- to SO2-dominated.