Experimental Measurements of Benzene Ice Critical Saturation Ratios on Titan Tholins and Impact on the Microphysical Modeling of Titan's South Polar Benzene Cloud

Abstract

The Cassini Composite Infrared Spectrometer (CIRS) revealed the presence of a benzene (C6H6) ice cloud in Titan's autumn south polar stratosphere, following the northern spring equinox in August 2009. This event increased the mixing ratio of benzene and raised the cloud top altitude. We present here new experimental measurements of the critical saturation (Scrit) of pure C6H6 ice at low temperature (from 13.8 at 138 K to 3.3 at 157 K), representative of Titan's atmospheric temperatures, when deposited onto Titan aerosol analogs (tholins) produced in the NASA Ames COsmic SImulation Chamber (COSmIC). Comparisons of Scrit values of benzene vapor deposition obtained on blank substrates versus on Titan tholins reveals the highly favorable role aerosols play as condensation nuclei. We have included these new Scrit measurements to calculate the nucleation contact parameter from m = 2.6e-4 T + 0.9494 in the Community Aerosol and Radiation Model for Atmospheres (CARMA) to investigate the variation in size and number density of C6H6 cloud particles as a function of altitude in Titan's southern polar atmosphere at 87 S. We discuss how these new temperature-dependent measurements impact the microphysical modeling and result in simulated benzene clouds forming about 20 km lower than seen in previous observations. A possible explanation for this discrepancy is that the cloud system was likely influenced by the co-condensation of more than one volatile gas species.