Optical Anisotropy and Phase Matching in Non-Centrosymmetric Perovskite Oxides from DFT+U and DFT+U+V Functionals

Abstract

Optical anisotropy underpins the operation and performance of a broad range of photonic and quantum technologies. In this work, we critically examine the accuracy of density functional theory approximations with onsite and intersite Hubbard corrections (the DFT+$U$ and DFT+$U$+$V$ functionals) in predicting the anisotropic optical response of the non-centrosymmetric perovskite oxides, such as BaTiO$_3$, LiNbO$_3$, KNbO$_3$, and PbTiO$_3$. It is found that correcting self-interaction errors using DFT+$U$ alone does not capture the optoelectronic response of these materials, often leading to a suppression of their optical anisotropy. While intersite Hubbard interactions restore this anisotropy, the choice of the (inter)atomic orbital manifold that defines the Hubbard correction remains critical to its accuracy. The predictive performance of the resulting, systematically validated DFT+$U$+$V$ functional is achieved at a fraction of the computational cost of hybrid functionals and many-body perturbation theory calculations. As benchmarks, we investigate Zn- and (Bi,Mn)-substituted BaTiO$_3$ solid solutions; the latter exhibit polarization-dependent bandgap narrowing from mid-gap states, substantially enhancing the dichroic ratio and birefringence with promising implications for polarization-sensitive photodetectors and integrated photonics.