Wet Removal and Cloud Enhancement: The Microphysics of Cloud-Haze Interactions on Sub-Neptunes

Abstract

Aerosols are a near-ubiquitous feature of sub-Neptune atmospheres, yet their microphysical nature remains poorly understood. Both condensate clouds and photochemical hazes have been proposed to explain observations, but have largely been studied in isolation. Here we present a new bin-scheme microphysical model, adapted from CARMA, that couples cloud and haze formation through heterogeneous nucleation - the dominant mode of cloud formation in the Solar System - in which haze particles act as cloud condensation nuclei (CCN). Applying this model to KCl clouds on GJ 1214 b-like warm sub-Neptunes, we find that the microphysical contact angle $\theta$ between cloud and haze particles governs distinct regimes of aerosol behavior: at moderate contact angles ($25^\circ \lesssim \theta \lesssim 70^\circ$), hazes are efficiently removed from the upper atmosphere through "wet removal" as they seed gravitationally-settling clouds; at small contact angles ($\theta \lesssim 25^\circ$), heterogeneous nucleation instead produces an enhanced population of mixed cloud-haze particles at high altitudes, dramatically increasing aerosol optical depth ("cloud enhancement"). These structural changes produce differences of up to four scale heights in transmission spectra, with strong effects at optical and near-infrared wavelengths relevant to JWST NIRISS/SOSS, while wavelengths beyond about 3 microns remain comparatively unaffected. We map these effects across orders of magnitude in metallicity, haze production rate, and vertical mixing strength, establishing their generality across sub-Neptune parameter space. Because heterogeneous nucleation is a universal phase-change process, this framework extends naturally to other exoplanet atmospheres and potentially any astrophysical environments where condensation onto foreign substrates may occur, including protoplanetary disks and stellar outflows.