A Variational Framework for Nonlinear Chemical Thermodynamics Employing the Maximum Energy Dissipation Principle

Adam Moroz

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arXiv · 2608.26843

A Variational Framework for Nonlinear Chemical Thermodynamics Employing the Maximum Energy Dissipation Principle

Adam Moroz

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Abstract

The maximum energy dissipation principle is employed to nonlinear chemical thermodynamics in terms of distance variable (generalized displacement) from the global equilibrium, applying the optimal control interpretation to develop a variational formulation. The cost-like functional was chosen to support the suggestion that such a formulation corresponds to the maximum energy dissipation principle. Using this approach, the variational framework was proposed for a nonlinear chemical thermodynamics, including general cooperative kinetics model. The formulation is in good agreement with standard linear non-equilibrium chemical thermodynamics.

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Adam Moroz. 2026-08-27. A Variational Framework for Nonlinear Chemical Thermodynamics Employing the Maximum Energy Dissipation Principle. https://arxiv.org/abs/2608.26843

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