A Sharpened Entropy Principle for Two-Fluid Polymer Thermodynamics

Abstract

A compressible, non-isothermal dilute polymer solution is formulated as a Class-II binary mixture with separate solvent and polymer mass and momentum balances and with total energy and entropy balances for the complete mixture. The entropy exploitation is sharpened by a balance-anchoring axiom introduced here: in a fixed balance representative, each selected binary dissipative product contains a constitutive factor from an unclosed balance flux or source. Polymer configuration is resolved first by a connector distribution and then by its conformation tensor. Population kinematics fix polymer transport and, by moments, yield a two-velocity upper-convected rate; objectivity verifies covariance rather than selecting it. Within the total entropy balance, configurational transport and deformation powers cancel their chemical-potential and elastic partial-stress counterparts when deformation and stress-decomposition weights match. A Gordon--Schowalter test independently requires the affine upper-convected choice for the stated dumbbell free energy and Kramers stress unless an additional reversible channel is supplied. Coordinated stress--interaction changes shift the local entropy flux/production pair by a divergence, exposing representation dependence of local mechanism-wise production. An entropy-invariant Class-II-to-Class-I reduction selects a descendant entropy flux preserving the parent production and yields thermo-chemical, configurational-stress and partial-viscous-stress diffusion terms. The omitted quadratic relative-inertia flux is paired with relative kinetic-energy storage and transport and is a reversible truncation, not missing entropy production. The resulting compressible non-isothermal Hookean stress and temperature equations reduce to Oldroyd-B/UCM only after one-velocity, incompressible and isothermal limits.