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arXiv · 2609.11340

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Kenshin Matsumoto·Shin-ichi Sasa
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Abstract

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

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Kenshin Matsumoto, Shin-ichi Sasa. 2026-09-10. Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation. https://arxiv.org/abs/2609.11340

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