ALMA Chemical Evolution (ACE) Survey: Molecular gas properties of low-mass, low-metallicity galaxies at cosmic noon

Abstract

Molecular gas plays a central role in regulating star formation and galaxy evolution, yet observational constraints at cosmic noon remain biased toward massive, metal-rich systems. We present ALMA Band 3 observations of the CO J=3-2 transition in 26 unlensed star-forming galaxies from the ALMA Chemical Evolution (ACE) Large Program at z~2-2.5, probing stellar masses of $10^{9} < M_\star < 10^{10.5}\,\mathrm{M}_{\odot}$ and sub-solar metallicities (8.2 < 12 + log(O/H) < 8.6). We derived molecular gas masses using a metallicity-dependent CO-to-H$_2$ conversion factor and alongside analysed stacking measurements and a homogenized literature compilation spanning both local and high-redshift galaxies. We find that the ACE galaxies extend established molecular-gas scaling relations to an order of magnitude lower stellar masses than previously explored at cosmic noon. The molecular gas mass ($M_{\rm mol}$) correlates tightly with star formation rate (SFR), while molecular gas fractions show a strong dependence on specific star formation rate (sSFR) and offset from the star-forming main sequence. In contrast, molecular gas fractions show only weak trends with stellar mass and no significant dependence on metallicity. Molecular gas depletion times are ~1 Gyr and vary little with stellar mass or metallicity, and weakly with sSFR and offset from the star-forming main sequence. Together this further reinforces that the availability of molecular gas is the primary driver of the SFR in galaxies, with changes in star-formation efficiency playing a secondary role. Leveraging the expanded parameter space probed by the ACE and literature samples, we derive a new empirical prescription for predicting $M_{\rm mol}$ as a function of SFR and sSFR. The persistence of the observed scaling relations suggests a largely universal framework governing the molecular gas-star formation cycle across cosmic time.