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arXiv · 2610.06283

First-Principles Investigation of Multimodal Toxic Gas Sensing in Carbon-Tuned hBN-Graphene Alloys: Chemiresistive, Work-Function, and Optical Responses

Tanjuma Shikder Jhumu·Ahmed Zubair
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Abstract

Compact, reliable, and cost-effective gas sensors have become a highly demanding subject for safety management in the medical sector, chemical manufacturing, food quality monitoring, agriculture, and industrial safety. Hazardous gas emissions need to be controlled and monitored with fast-responsive and highly sensitive sensing devices. A first-principles study employing density functional theory (DFT) was used to investigate the adsorption behavior of Cl2, CO, CO2, NO, NO2, and HCN gas molecules with our proposed alloys, which consisted of hexagonal boron nitride (hBN) and graphene (Gr). The alloy consisting of 22% carbon (BNGr-2) was found to be most competent for sensing Cl2, CO, CO2, and HCN with sufficient adsorption energy, charge transfer, and bandgap alteration. However, NO and NO2 gas molecules showed more engagement with 33% carbon-proportioned alloy (BNGr-3) in terms of adequate gas sensing properties. NOx gases exhibited the most chemiresistive sensitivity towards the adsorbents. Other gases also showed significant chemiresistive sensitivity and distinct selectivity ratios, which would facilitate these alloys as chemiresistive sensors. Besides, noticeable work function variation (~20%) of these systems manifested potential as work function based sensors. Cl2 and NO2 showed strong physical adsorption, while the rest of the gases were weakly to moderately physisorbed, resulting in very short recovery times (10-1 ~ 10-6 seconds). Additionally, the distinctive absorption spectra observed for the gas analyte systems highlighted the potential of the proposed alloys as optical gas sensors. Temperature variation revealed that all gas molecules can be freed from the adsorbent BNGr-2 at 425 K. These findings imply hBN-Gr alloys as promising gas sensors for pollution auditing.

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Tanjuma Shikder Jhumu, Ahmed Zubair. 2026-10-05. First-Principles Investigation of Multimodal Toxic Gas Sensing in Carbon-Tuned hBN-Graphene Alloys: Chemiresistive, Work-Function, and Optical Responses. https://arxiv.org/abs/2610.06283

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