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arXiv · 2611.08965

Evaporation-induced colloidal diffusiophoresis in electrolyte solutions

Dang Q. Duong·Jung Hyun Kim·Hanna Cho·Sangwoo Shin
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Abstract

Non-volatile solutes accumulate near a receding drying front, generating concentration gradients that can drive directional colloidal transport by diffusiophoresis. This dynamic spatial arrangement of colloidal particles could affect the microstructure and macroscopic properties of the dried film. Here, we combine experiments and theory to investigate polystyrene particles suspended in electrolyte solutions drying within a capillary tube. By varying the electrolyte composition and ambient relative humidity, we show that evaporation-induced ion gradients drive particles toward the liquid-gas interface and enhance interfacial accumulation, whereas slower drying at higher humidity weakens the gradient and particle migration. We use the heat balance integral method to predict the transient solute field for a receding interface and couple it to particle transport to capture the observed particle trajectories and accumulation trends. These results identify background electrolytes and drying rate as coupled controls on particle distribution and provide a predictive framework to optimize formulation and processing parameters for manufacturing slurry-based materials, such as battery electrodes and turbine coatings.

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Dang Q. Duong, Jung Hyun Kim, Hanna Cho, Sangwoo Shin. 2026-11-06. Evaporation-induced colloidal diffusiophoresis in electrolyte solutions. https://arxiv.org/abs/2611.08965

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