Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · astro-ph/0506032

Silicon Tetrafluoride on Io

Laura Schaefer·Bruce Fegley Jr
View original source ↗Read source document ↗Export metadata ↓

Abstract

Silicon tetrafluoride (SiF4) is observed in terrestrial volcanic gases and is predicted to be the major F - bearing species in low temperature volcanic gases on Io (Schaefer and Fegley, 2005b). SiF4 gas is also a potential indicator of silica-rich crust on Io. We used F/S ratios in terrestrial and extraterrestrial basalts, and gas/lava enrichment factors for F and S measured at terrestrial volcanoes to calculate equilibrium SiF4/SO2 ratios in volcanic gases on Io. We conclude that SiF4 can be produced at levels comparable to the observed NaCl/SO2 gas ratio. We also considered potential loss processes for SiF4 in volcanic plumes and in Io's atmosphere including ion-molecule reactions, electron chemistry, photochemistry, reactions with the major atmospheric constituents, and condensation. Photochemical destruction (tchem ~ 266 days) and/or condensation as Na2SiF6 (s) appear to be the major sinks for SiF4. We recommend searching for SiF4 with infrared spectroscopy using its 9.7 micron band as done on Earth.

Explore related subjects

astro-ph

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Laura Schaefer, Bruce Fegley Jr. 2005-06-01. Silicon Tetrafluoride on Io. https://doi.org/10.1016/j.icarus.2005.05.020

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2023

Dark Energy is the Cosmological Quantum Vacuum Energy of Light Particles-The Axion and the Lightest Neutrino

We uncover the general mechanism producing the dark energy(DE). This is only based on well known quantum physics and cosmology. We show that the observed DE originates from the cosmological quantum vacuum of light particles which provides a continuous energy distribution able to reproduce the data. Bosons give positive contributions to the DE while fermions yield negative contributions. As usual in field theory, ultraviolet divergences are subtracted from the physical quantities. The subtractions respect the symmetries of the theory and we normalize the physical quantities to be zero for the Minkowski vacuum. The resulting finite contributions to the energy density and the pressure from the quantum vacuum grow as log a(t) where a(t) is the scale factor, while the particle contributions dilute as 1/a^3(t), as it must be for massive particles. The DE equation of state P = w(z)H turns to be w(z)<-1 with w(z) asymptotically reaching the value -1 from below.A scalar particle can produce the observed DE through its quantum cosmological vacuum provided:(i)its mass is of the order of 10^{-3} eV = 1 meV,(ii) it is very weakly coupled and (iii) it is stable on the time scale of the age of the universe. The axion vacuum thus appears as a natural candidate. The neutrino vacuum (especially the lightest mass eigenstate) can give negative contributions to the DE. We find that w(z=0) is slightly below -1 by an amount ranging from [-1.5 10^{-3}] to [-8 10^{-3}] and we predict the axion mass to be in the range between 4 and 5 meV. We find that the universe will expand in the future faster than the de Sitter universe, as an exponential in the square of the cosmic time. DE arises from the quantum vacua of light particles in FRW cosmological space time in an analogous way to the Casimir effect in Minkowski spacetime with non trivial boundaries.

astro-ph↗
arXiv2023

Scaling of Black Hole Accretion Discs from Gamma-Ray Bursts and Black Hole X-Ray Binaries to Active Galactic Nuclei

I consider how physical processes scale over eight orders of magnitude in black hole mass, from stellar masses in gamma-ray bursts (GRB) and black-hole X-ray binaries (BHXRB) to supermassive active galactic nuclei (AGN). Accretion rates onto stellar mass black holes range over more than sixteen orders of magnitude, from the lower luminosity BHXRB to GRB. These enormous parameter ranges correspond to qualitative as well as quantitative differences in behavior. The fundamental questions involve the balance between nonequilibrium and thermalized plasmas. When energy fluxes exceed a critical value $\sim 10^{29}$ erg/cm$^2$s, as in GRB, a black-body equilibrium pair plasma forms. At the lower fluxes found in AGN, BHXRB and microquasars, accretion power electrodynamically accelerates a small number of very energetic particles, explaining their non-thermal spectra and the high energy gamma-ray emission of blazars. Ultra-high energy cosmic rays may be accelerated by massive black holes, otherwise undetectable, with very low thermal luminosities. New-born fast high-field pulsars may be in the black-body equilibrium regime, resembling SGR in permanent outburst. I also consider the question, significant for the acceleration of nonthermal particles in GRB outflows, of whether collisionless plasmas interpenetrate rather than forming hydrodynamic shocks, and propose this as an alternative to internal shock models of GRB. A new appendix attempts to explain why AGN are, proportionally, more efficient accelerators of energetic particles than stellar mass black holes.

astro-ph↗