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Strong ferromangnetism and weak antiferroamgnetism in double perovskites: Sr$_2$Fe{/it M}O$_6$ ({/it M}=Mo, W and Re)

Z. Fang·K. Terakura·J. Kanamori
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Abstract

Double perovskites Sr$_2$FeMO$_6$ (M=Mo and Re) exhibit significant colossal magnetoresistance even at room temperature due to the high Curie Temperature (419K and 401K). However, such a high Curie Temperature is puzzling, given the large separation between magnetic elements (Fe). Moreover, with M=W, the electronic and magnetic properties suddenly change to insulating and antiferromagnetic with the N{é}el temperature of only 16$\sim$37 K. Based on detailed electronic structure calculations, a new mechanism is proposed which stabilizes the strong ferromagnetic state for M=Mo and Re and is passivated for M=W.

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Z. Fang, K. Terakura, J. Kanamori. 2001-03-08. Strong ferromangnetism and weak antiferroamgnetism in double perovskites: Sr$_2$Fe{/it M}O$_6$ ({/it M}=Mo, W and Re). https://doi.org/10.1103/physrevb.63.180407

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