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The Smectic Phase of Spherical-Fan Shaped Molecules. A Computer Simulation Study

A. G. Vanakaras·D. J. Photinos
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Abstract

We have used Monte Carlo NPT computer simulations to study a system of spherical fan shaped particles made of three hard discs fused along a common diameter. The calculated equation of state indicates a strong, entropy driven, first order transition from the isotropic phase to a layered phase that has the basic characteristics of the usual smectic A mesophase but with strongly correlated rotations about the symmetry axes of neighbouring molecules.

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A. G. Vanakaras, D. J. Photinos. 2001-03-25. The Smectic Phase of Spherical-Fan Shaped Molecules. A Computer Simulation Study. https://doi.org/10.1016/s0009-2614(01)00443-2

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