Anomalous transverse acoustic phonon broadening in the relaxor ferroelectric Pb(Mg_1/3Nb_2/3)O_3

Abstract

The intrinsic linewidth $Γ_{TA}$ of the transverse acoustic (TA) phonon observed in the relaxor ferroelectric compound Pb(Mg$_{1/3}$Nb$_{2/3})_{0.8}$Ti$_{0.2}$O$_3$ (PMN-20%PT) begins to broaden with decreasing temperature around 650 K, nearly 300 K above the ferroelectric transition temperature $T_c$ ($\sim 360$ K). We speculate that this anomalous behavior is directly related to the condensation of polarized, nanometer-sized, regions at the Burns temperature $T_d$. We also observe the ``waterfall'' anomaly previously seen in pure PMN, in which the transverse optic (TO) branch appears to drop precipitously into the TA branch at a finite momentum transfer $q_{wf} \sim 0.15$ Å$^{-1}$. The waterfall feature is seen even at temperatures above $T_d$. This latter result suggests that the PNR exist as dynamic entities above $T_d$.