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Critical behavior of the restricted primitive model revisited

J. -M. Caillol·D. Levesque·J. -J. Weis
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Abstract

Reassessment of the critical temperature and density of the restricted primitive model of an ionic fluid by Monte Carlo simulations performed for system sizes with linear dimension up to $L/σ=34$ and sampling of $\sim 10^9$ trial moves leads to $T^*_c=0.04917 \pm 0.00002$ and $ρ_c^* =0.080 \pm 0.005$. Finite size scaling analysis based in the Bruce-Wilding procedure gives critical exponents in agreement with those of the 3d Ising universality class. An analysis similar to that proposed by Orkoulas et al [Phys. Rev. E 63, 051507 (2001)], not relying on an a priori knowledge of the universality class, leads to an unaccurate estimate of $T_c^*$ and to unexpected behavior of the specific heat and value of the critical exponent ratio $γ/ν$.

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J. -M. Caillol, D. Levesque, J. -J. Weis. 2002-03-20. Critical behavior of the restricted primitive model revisited. https://doi.org/10.1063/1.1480009

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