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V-V Bond-Length Fluctuations in Vox

J. B. Goodenough·F. Rivadulla·E. Winkler·J. -S. Zhou
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Abstract

We report a significantly stronger suppression of the phonon contribution to the thermal conductivity in VOx than can be accounted for by disorder of the 16 % atomic vacancies present in VO. Since the transition from localized to itinerant electronic behavior is first-order and has been shown to be characterized by bond-length fluctuations in several transition-metal oxides with the perovskite structure, we propose that cooperative V-V bond-length fluctuations play a role in VO similar to the M-O bond-length fluctuations in the perovskites. This model is able to account for the strong suppression of the thermal conductivity, the existence of a pseudogap confirmed by thermoelectric power, an anomalously large Debye-Waller factor, the temperature dependence of the magnetic susceptibility, and the inability to order atomic vacancies in VO.

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J. B. Goodenough, F. Rivadulla, E. Winkler, J. -S. Zhou. 2002-11-11. V-V Bond-Length Fluctuations in Vox. https://doi.org/10.1209/epl%2Fi2003-00161-8

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