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The Smallest Molecular Switch

Eldon G. Emberly·George Kirczenow
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Abstract

Ab-initio total energy calculations reveal benzene-dithiolate (BDT) molecules on a gold surface, contacted by a monoatomic gold STM tip to have two classes of low energy conformations with differing symmetries. Lateral motion of the tip or excitation of the molecule cause it to change from one conformation class to the other and to switch between a strongly and a weakly conducting state. Thus, surprisingly, despite their apparent simplicity these Au/BDT/Au nanowires are shown to be electrically bi-stable switches, the smallest two-terminal molecular switches to date. Experiments with a conventional or novel self-assembled STM are proposed to test these predictions.

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Eldon G. Emberly, George Kirczenow. 2003-01-16. The Smallest Molecular Switch. https://doi.org/10.1103/physrevlett.91.188301

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