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Thermodynamics of micellization of oppositely charged polymers

Martin Castelnovo
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Abstract

The complexation of oppositely charged colloidal objects is considered in this paper as a thermodynamic micellization process where each kind of object needs the others to micellize. This requirement gives rise to quantitatively different behaviors than the so-called mixed-micellization where each specie can micellize separately. A simple model of the grand potential for micelles is proposed to corroborate the predictions of this general approach.

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Martin Castelnovo. 2003-04-16. Thermodynamics of micellization of oppositely charged polymers. https://doi.org/10.1209/epl%2Fi2003-00449-1

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