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Thermodynamic calculations on the catalytic growth of multiwall carbon nanotubes

Christian Klinke·Jean-Marc Bonard·Klaus Kern
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Abstract

We have developed a thermodynamic model of the catalytic growth of multiwall carbon nanotubes from hydrocarbon precursors at elevated temperature. Using this model we have computed the heat distribution, and carbon concentration in the catalyst. Calculations delivered a analytical formula for the growth time and growth rate. We find that the growth is mainly driven by a concentration gradient within the catalyst, rather than a temperature gradient.

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Christian Klinke, Jean-Marc Bonard, Klaus Kern. 2005-11-30. Thermodynamic calculations on the catalytic growth of multiwall carbon nanotubes. https://doi.org/10.1063/1.1628069

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